Download Advances in Chemical Physics, Volume 2 by K. P. Lawley PDF

By K. P. Lawley

ISBN-10: 0470697954

ISBN-13: 9780470697955

The Advances in Chemical Physics sequence offers the chemical physics and actual chemistry fields with a discussion board for serious, authoritative reviews of advances in each region of the self-discipline. jam-packed with state of the art learn stated in a cohesive demeanour now not discovered somewhere else within the literature, every one quantity of the Advances in Chemical Physics sequence serves because the excellent complement to any complex graduate category dedicated to the research of chemical physics.

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Evaluation of the Cell Partition Function by the Method of Lennard-Jones and Devonshire The partition functions (Eq. 4 ) and the resulting expressions for the properties of the clathrate contain the cell partition functions hJl as the only unknowns. If it were possible to construct these parti- 24 J. H. VAN DER WAALS AND J. C. PLATTEEUW tion functions, the thermodynamic behavior of clathrates relative to the empty @ lattice might be predicted. 51Because the application of this method to the present problem has been described in detai1,5, we shall restrict ourselves to its most essential features.

12. Forcrand, R. de, comp. rend. 134,835, 991 (1902); 135, 959 (1902). 13. Fowler, R. , and Guggenheim, E. , Statistical Thermodynamics, University Press, Cambridge, 1952. 14. Guggenheim, E. A,, Boltzmann’s Distribution L a w , North-Holland, Amsterdam, Interscience, New York, 1955, pp. 47, 48. 15. Hirschfelder, J . , Curtiss, Ch. , and Bird, R. , Molecular Theory of Gases and Liquids, Wiley & Sons, New York, 1954, pp. 1110, 1111. 16. Korvezee, A. , and Scheffer, F. E. , Rec. trav. chim. 50,256 (1931).

Waals, J . H. van der, Faraday Soc. Discussions 15, 261 (1953). 52. VC'aals, J . H. van der, T r a n s . Faraday Soc. 52, 184 (1956). 53. Waals, J. H. van der, and Platteeuw, J . , Rec. trav. chim. 75, 912 (1956). 54. Wentorf, R. , Buehler, R. , Hirschfelder, J . , and Curtiss, C. , J . Chem. P h y s . 18, 1484 (1950). 55. Wells, A. , T h e T h i r d Dimension in Chemistry, Clarendon Press, Oxford, 1956. 56. , arid Schneider, W. , J . C h e w . P h y s . 23, 1644 (1955). 57. Wilcox, W. , Carson, D.

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